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3D-Honeycombed CL-20 structures with low critical size of detonation have been fabricated successfully for intelligent weapon systems using a micro-flow direct ink writing (DIW) technology. The CL-20-based explosive ink for DIW technology was prepared by a two-component adhesive system with waterbe polyurethane (WPU) and ethyl cellulose (EC). Not only the preparation of the explosive ink but also the principle of DIW process have been investigated systematically. The explosive ink displayed strong shear-thinning behavior that permitted layer-by-layer deposition from a fine nozzle onto a substrate to produce complex shapes. The EC content was varied to alter the pore structure distribution and rheological behavior of ink samples after curing. The deposited explosive composite materials are of a honeycombed structure with high porosity, and the pore size distribution increases with the increase of EC content. No phase change was observed during the preparation process. Both WPU and EC show good compatibility with CL-20 particles. Apparently high activation energy was realized in the CL-20-based composite ink compared with that of the refined CL-20 due to the presence of non-energetic but stable WPU. The detonation performance of the composite materials can be precisely controlled by an adjustment in the content of binders. The 3D honeycombed CL-20 structures, which are fabricated by DIW technology, have a very small critical detonation size of less than 69μm, as demonstrated by wedge shaped charge test. The ink can be used to create 3D structures with complex geometries not possible with traditional manufacturing techniques, which presents a bright future for the development of intelligent weapon systems.