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(Cudpt) (ClO4) 2 和K4[Fe(CN) 6]反应得到配位聚合物 (Cudpt) 3 [Fe(CN) 6](ClO4) 2 ·3H2 O(1 ) ,在相似条件下用Cu(ClO4) 2 ,dpt和K4[Fe(CN) 6]反应得到配位聚合物 (Cudpt3 [Fe(CN) 6](ClO4) 2 ·4H2 O(2 ) ,解析了它们的晶体结构。这两个化合物有相同的I.R .和UV—Vis谱 ,但它们的结构却有显著的不同 ,前者是一维链状结构 ,后者则是二维网状结构。
(Cudpt) 3 [Fe (CN) 6] (ClO4) 2 · 3H2O (1) was obtained by the reaction of Cudpt (ClO4) 2 with K4 [Fe (CN) 6] The crystal structure of Cudpt3 [Fe (CN) 6] (ClO4) 2 · 4H2O (2) was obtained by the reaction of (ClO4) 2, dpt and K4 [Fe (CN) 6] The compounds have the same IR. And UV-Vis spectra, but their structures are significantly different, the former is a one-dimensional chain structure, while the latter is a two-dimensional network structure.