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本文首次用超过滤法测定了有机显色剂CAS、PAR、TAMB、BTAMB.金属离子Ni(?)和Ni(Ⅱ)-TAMB配合物在SDBS、SDS、CTMAB、Triton X-100、Brij35及PeregalO等胶束溶液中的分配系数。较详细地研究了超过滤条件,根据所得数据,并将其与相应光度体系的行为进行了比较。得出了一些有意义的结论。文中还利用分配系数定义式,推得了旨在计算溶质在胶束一水相分配比值的方程,并将所得结果与光度体系中配合物在胶束存在下的褪色现象,最佳表面活性剂用量范围与配合物稳定常数关系进行了比较.得出了一些结论和规律。
In this paper, the organic chromogenic agents CAS, PAR, TAMB and BTAMB were determined by ultrafiltration method for the first time.The complexes of Ni (Ⅱ) -TAMB and Ni (Ⅱ) -TAMB were immobilized on SDBS, SDS, CTMAB, Triton X-100, Brij35 and PeregalO Such as micellar solution in the partition coefficient. The ultrafiltration conditions were investigated in more detail and based on the data obtained, their behavior was compared with that of the corresponding photometric system. Come to some meaningful conclusions. In this paper, we also use the definition of partition coefficients to deduce the equation that is used to calculate the ratio of solute to water in micelles, and the results obtained are in agreement with the fade phenomenon of the complex in the photometric system in the presence of micelles. The optimum amount of surfactant The relationship between the stability of the complex and the complex was compared. Some conclusions and laws were obtained.