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本文对地矿部“海洋四号”科学考察船1987—1989年在东赤道太平洋CC区所取得的27个深海表层沉积物样品进行U的地球化学分析,探讨了U在深海沉积中的地球化学行为。结果表明,不同类型沉积物的U含量不同,平均值由大至小的次序为含沸石粘土(2.16×10 ̄(-6))、硅质粘土(1.95×10 ̄(-6)),硅质软泥(1.65×10 ̄(-6))、钙质硅质粘土(1.59×10 ̄(-6)),在同类型沉积物中U的分散性较大;U在区域上的分布趋势与Corg类似而与CaCO_3相反,呈现出由南向北降低的趋势。与大陆边缘海、封闭、半封闭海的沉积物相比,深海沉积物的U含量最低,表现出U的亏损;U的晶体化学性质以及沉积物的物质来源决定了深海沉积物的U来源于海水和陆地,海水来源的U被自生粘土矿物和有机质吸附,陆源U与陆源粘土矿物有关,而较高的Eh和较低的Corg以及生物碎屑组份SiO_2、CaCO_3和P_2O_5对它起稀释作用都导致U的亏损,同时,U和Th较大程度的分异也是深海沉积物的主要标志。
In this paper, 27 deep-sea surface sediment samples obtained from the “Ocean No. 4” scientific research ship in the Eastern equatorial Pacific CC from 1987 to 1989 were analyzed for geochemistry, and the geochemical characteristics of U in deep-sea sediments behavior. The results show that the contents of U in different types of sediments are different. The average order of the contents of the sediments is zeolite clay (2.16 × 10 ~ (-6)), siliceous clay (1.95 × 10 ~ (-6) ), Siliceous slime (1.65 × 10 ~ (-6)), and calcareous siliceous clay (1.59 × 10 ~ (-6)). The dispersibility of U in the sediments of the same type is larger ; The distribution trend of U in the area is similar to that of Corg but opposite to that of CaCO_3, showing a decreasing trend from south to north. Compared with the sediments in the coastal, closed and semi-closed continent of the continental margin, the sediments in deep sea have the lowest content of U and show the loss of U. The crystal chemistry of U and the source of sediment determine the origin of U land and sea, sea water is derived from the U raw clay minerals and organic matter adsorption, U and terrigenous terrestrial clay minerals, whereas a higher Eh and lower parts and Corg bioclast group SiO_2, CaCO_3 dilution effect and play it P_2O_5 All lead to the loss of U. Meanwhile, the greater degree of differentiation of U and Th is also the main sign of deep-sea sediments.