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I-doped titanium dioxide nanospheres(I-TNSs) were synthesized via a two-step hydrothermal synthesis route,their potential for the efficient utilization of visible light was evaluated.The prepared anatase-phase I-TNSs had a bimodal porous size distribution with a Brunauer-Emmett-Teller surface area of 76 m2/g,a crystallite size of approximately 14 nm calculated from X-ray diffraction data,and a remarkable absorption in the visible light region at wavelengths > 400 nm.The photocatalytic activity of the samples was evaluated by decoloration of Methyl Orange in aqueous solution under visible light irradiation in comparison to the iodine-doped TiO2(I-TiO2).The I-TNSs showed higher photocatalytic efficiency compared with I-TiO2 after irradiation for 180 min even though the latter had a much greater surface area(115 m2/g).It was concluded that the surface area was not the predominant factor determining photocatalytic activity,and that the good crystallization and bimodal porous nanosphere structure were favourable for photocatalysis.
I-doped titanium dioxide nanospheres (I-TNSs) were synthesized via a two-step hydrothermal synthesis route, their potential for the efficient utilization of visible light was evaluated. The prepared anatase-phase I-TNSs had a bimodal porous size distribution with a Brunauer-Emmett-Teller surface area of 76 m2 / g, a crystallite size of approximately 14 nm calculated from X-ray diffraction data, and a remarkable absorption in the visible light region at wavelengths> 400 nm. The photocatalytic activity of the samples was evaluated by decoloration of Methyl Orange in aqueous solution under visible light irradiation in comparison to the iodine-doped TiO2 (I-TiO2). The I-TNSs took higher photocatalytic efficiency compared with I-TiO2 after irradiation for 180 min even though the latter had a much greater surface area (115 m2 / g). It was concluded that the surface area was not the predominant factor sorted photocatalytic activity, and that the good crystallization and bimodal porous nanosphere str ucture were favorable for photocatalysis.