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The addition of allyltrimethylsilane to tert-butanesulfinyl imines triggered by tetra-n- butylammonium fluoride (TBAF) in the presence of 4A molecular sieves has been studied, and homoallylsulfinamides were obtained in good yields with moderate to high diastereoselectivities.
The addition of allyltrimethylsilane to tert-butanesulfinyl imines triggered by tetra-n- butylammonium fluoride (TBAF) in the presence of 4A molecular sieves has been studied, and homoallylsulfinamides were obtained in good yield with moderate to high diastereoselectivities.