液液液三相萃取装置:操作参数对传质效率的影响(英文)

来源 :Chinese Journal of Chemical Engineering | 被引量 : 0次 | 上传用户:strengthandhonor
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A new mixer-settler-mixer three chamber integrated extractor is proposed in this work for liquid-liquid-liquid three phase countercurrent and continuous extraction.Experiments revealed the influences of the structural design of the three-liquid-phase extractor and some key operational parameters on three-phase partition of two phenolic isomers,p-nitrophenol(p-NP) and o-nitrophenol(o-NP).The model three-liquid-phase extraction system used here is nonane(organic top-phase)-polyethylene glycol(PEG 2000)(polymer middle-phase)-(NH4)2SO4 aqueous solution(aqueous bottom-phase).It is indicated that agitating speed and retention time in three-phase mixer are key parameters to extraction fraction of nitrophenol.Dispersion band behavior is related to agitating in-tensity,and its occurrence does not affect the extraction fraction of target compounds.The present work highlights the possibility of a feasible approach of scaling up of the proposed three-phase extraction apparatus for future in-dustrial-aimed applications. A new mixer-settler-mixer three chamber integrated extractor is proposed in this work for liquid-liquid-liquid three phase countercurrent and continuous extraction. Experiments the influence of the structural design of the three-liquid-phase extractor and some key operational parameters on three-phase partition of two phenolic isomers, p-nitrophenol (p-NP) and o-nitrophenol (o-NP). The model three-liquid-phase extraction system used here is nonane (organic top- (PEG 2000) (polymer middle-phase) - (NH4) 2SO4 aqueous solution (aqueous bottom-phase) .It is indicated that agitating speed and retention time in three-phase mixer are key parameters to extraction fraction of nitrophenol. Dispersion band behavior is related to agitating in-tensity, and its occurrence does not affect the extraction fraction of target compounds. present work highlights the possibility of a feasible approach of scaling up of the proposed three-phase extraction apparatus for future in-dustri al-aimed applications.
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