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采用多种核磁共振技术测定了一种重要有机膦酸2-磷酸基丁烷-1,2,4三核酸(PBTC)的分子结构,发现其分子中至少存在着2对不等价同碳质子;测取了分子中各磁性核之间的偶合常数,并依靠这些数据解释了有关谱峰的形状特点;归属了PBTC工业产品中的杂质峰,并解释了PBTC各谱峰随浓度改变而发生位移的原因。
A variety of NMR techniques were used to determine the molecular structure of PBTC, an important organic phosphonic acid butane-1,2,4-tric acid (PBTC). It was found that there are at least two pairs of unequal equivalents of carbon proton ; Measured the coupling constants between the magnetic nuclei in the molecule and relied on these data to explain the shape characteristics of the peaks; assigned the impurity peaks in the PBTC industrial product and explained that the PBTC peaks peaked at varying concentrations The reason for the displacement.