Synthesis, Structure and Magnetic Property of One Ni~Ⅱ Based Coordination Polymer

• 作 者: 文博 王晓丹 于颖慧 高金胜 侯广峰
• 机 构: Engineering Research Centre of Pesticide of Heilongjiang University,Heilongjiang University,School o
• 出 处: 结构化学
• 发表日期: 2014年11期
• 关键词: topological structurally belongs monoclinic benzene connected Heilongjiang gravi

One new coordination polymer, [Ni(m-bix)(m-BDC)](1, m-bix = 1,3-bis(imidazol-1-ylmethyl)benzene, m-BDC = 1,3-benzenedicarboxylic acids), has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TGA and X-ray single-crystal diffraction. The green block crystal of complex 1(C22H18N4Ni O4) belongs to monoclinic system, space group P21/c with a = 10.0418(3), b = 23.8651(6), c = 8.7872(2) A, β = 112.333(3)o, V = 1947.88(9)A3, Z = 4, Dc = 1.572 g/cm3, Mr = 461.11, F(000) = 952, R = 0.0335 and w R = 0.0683 for 2827 observed reflections(I > 2σ(I)). Complex 1 exhibits a novel 6-connected 3D sxd type topological framework. The magnetic characterization of complex 1 shows antiferromagnetic coupling exchange.

One new coordination polymer, [Ni (m-bix) (m-BDC)] (1, m-bix = 1,3- bis (imidazol- 1 -ylmethyl) benzene, m- BDC = 1,3-benzenedicarboxylic acids) , has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TGA and X-ray single-crystal diffraction. The green block crystal of complex 1 (C22H18N4Ni O4) belongs to monoclinic system, space group P21 / c with a = 10.0418 ( B = 23.8651 (6), c = 8.7872 (2) A, β = 112.333 (3) o, V = 1947.88 (9) A3, Z = 4, Dc = 1.572 g / cm3, Mr = 461.11, F (000) = 952, R = 0.0335 and w R = 0.0683 for 2827 observed reflections (I> 2σ (I)). Complex 1 exhibits a novel 6-connected 3D sxd type topological framework. The magnetic characterization of complex 1 shows the antiferromagnetic coupling exchange.