Synthesis and Novel Properties of Alkyl Thiophosphoramidate Derivatives of Nucleosides

来源 :Chinese Journal of Chemistry | 被引量 : 0次 | 上传用户:fly_songs
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Novel alkyl thiophosphoramidate derivatives of nucleoside analogues (5) have been prepared by phosphochloridothioate chemistry. O Isopropyl 2′,3′ O isopropylidene uridine 5′ yl N thiophosphoryl threonine and serine methyl esters (5a and 5b) underwent the intramolecular catalyzed hydrolysis reaction. Novel alkyl thiophosphoramidate derivatives of nucleoside analogues (5) have been prepared by phosphochloridothioate chemistry. O Isopropyl 2 ’, 3’ O isopropylidene uridine 5 ’yl N thiophosphoryl threonine and serine methyl esters (5a and 5b) underwent the intramolecular catalyzed hydrolysis reaction.
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