Catalytic Combustion of Methane over Co_(1-x)Mg_xO/Al_2O_3/FeCrAl Monolithic Catalysts

来源 :Journal of Natural Gas Chemistry | 被引量 : 0次 | 上传用户:evemxy
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
A series of Co1-xMgxO/Al2O3/FeCrAl catalysts (x=0-1) were prepared. The structures of the catalysts were characterized using XRD, SEM, and TPR analyses. The catalytic activity of the catalysts for methane combustion was evaluated in a continuous flow microreactor. The results indicated that the active washcoats adhered well on the FeCrAl foils. The phases in the catalysts were Co1-xMgxO solid solutions,α-Al2O3, andγ-Al2O3. The surface particle size of the catalysts varied with variations in the molar ratios of Co to Mg. The Co component of the Co1-xMgxO/Al2O3/FeCrAl catalysts played an important role in the catalytic activity for methane combustion. In the Co1-xMgxO/Al2O3/FeCrAl series catalyst (x=0.2-0.8), the catalytic activity in terms of x was in the order of 0.5>0.2>0.8 under the experimental conditions. The presence of Mg in these catalysts could promote the thermal stability to a large extent. There were strong interactions between the Co1-xMgxO oxides and the supports. The series of Co1-xMgxO / Al2O3 / FeCrAl catalysts (x = 0-1) were prepared. The structures of the catalysts were characterized using XRD, SEM, and TPR analyzes. The catalytic activity of the catalysts for methane combustion was evaluated in a The results indicated that the active washcoats adhered well on the FeCrAl foils. The phases in the catalysts were Co1-xMgxO solid solutions, α-Al2O3, and γ-Al2O3. The surface particle size of the catalysts varied with variations in the The Co component of the Co1-xMgxO / Al2O3 / FeCrAl bass plays an important role in the catalytic activity for methane combustion. In the Co1-xMgxO / Al2O3 / FeCrAl series catalyst (x = 0.2-0.8) , the catalytic activity in terms of x was in the order of 0.5> 0.2> 0.8 under the experimental conditions. The presence of Mg in these resins could promote the thermal stability to a large extent. There were strong interactions between the Co1-xMgxO oxides and the supports
其他文献
期刊
在21世纪的今天,计算机在各方面都充当了重要的核心角色,因此,想要成为现代社会的应用型人才必须熟练掌握基本的计算机知识。在教学中必须通过教育学习使学生掌握计算机应用
青光眼滤过手术失败的最主要原因是滤过泪瘢痕形成,使滤过受阻。抗代谢药物的应用,使青光眼手术的成功率大大提高,但易引起角结膜毒性反应。这多用于有失败危险因素的青光眼。对
对于即将迎来校园生活的学生来讲,购置一部实用的笔记本显得尤为重要。价格不要太贵,屏幕不能太小,还能玩游戏……这些使用要求,都让学生用户在购买本本时显得焦头烂额,因此,
在去职联想集团董事局主席后,柳传志把自己的位置放在了联想控股的战略性投资上,现在的他更像是一位智慧的“大家长”,依旧以“常青树”的姿态执掌着这家目前中国最成功的企
廉政,是指国家政权机关及其官员的政治活动要廉洁,即为政清廉。“不受曰廉,不污曰洁”,意思是指不贪不受,清正无私。廉洁通常被看作是一种为官者的精神品格和道德标准,既指为官者个
Two new bimetallic cyano-bridged complexes [Ce(DMSO)4(H2O)3Fe(CN)6]·H2O 1 and [La(DMSO)4(H2O)3Co(CN)6]·H2O 2 have been prepared by the ball milling reaction m
泪道外伤后常致泪道闭塞而溢泪,治疗较困难。我院自lop年开始采用黄金泪管作泪湖鼻腔置管术治疗18例Xi眼,疗效满意,现报道如下。临床资料:本组18例Xi眼,男门例4眼,女7例8眼;年龄L-53
近日,财政部安排拨付中央财政专项扶贫资金307.01亿元,加上2016年10月提前下达的553.94亿元,截至目前,2017年预算安排补助地方中央财政专项扶贫资金860.95亿元已全部拨付地方
The coordination polymer {[Co(phth)(phen)(H2O)]·(C2H5OH)}n (phth = phthala- te, phen = 1,10-phenanthroline) with formula C22H20CoN2O6 (Mr = 467.33) was synthes