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The coordination polymer {[Co(phth)(phen)(H2O)]·(C2H5OH)}n (phth = phthala- te, phen = 1,10-phenanthroline) with formula C22H20CoN2O6 (Mr = 467.33) was synthesized by the solvothermal method under low temperature, and its crystal structure was determined by single- crystal X-ray diffraction. The complex belongs to monoclinic system, space group P21/n with a = 12.7352(16), b = 8.8125(11), c = 18.677(2) , β = 102.633(2)o, V = 2045.3(4) 3, Z = 4, Dc = 1.518 g/cm3, μ = 0.882 mm-1, F(000) = 964, S = 1.053, the final R = 0.0401 and wR = 0.0984 for 3135 observed reflections (I > 2σ(I)). Single-crystal X-ray analysis revealed that the Co(II) ion is six-coordinated. The cobalt complex forms a one-dimensional chain structure via phthalate bri- dging ligand. In the cobalt complex, a 3D network structure is formed by π-π stacking interaction of 1,10-phenanthroline as well as intermolecular hydrogen bonding interactions.
The coordination polymer {[Co (phth) (phen) (H2O)] · (C2H5OH)} n (phth = phthala- te, phen = 1,10-phenanthroline) with synthesized C22H20CoN2O6 (Mr = 467.33) was synthesized by the solvothermal method under low temperature, and its crystal structure was determined by single-crystal X-ray diffraction. The complex belongs to monoclinic system, space group P21 / n with a = 12.7352 (16), b = 8.8125 (2) β, β = 102.633 (2) o, V = 2045.3 (4) 3, Z = 4, Dc = 1.518 g / cm3, μ = 0.882 mm-1, F , the final R = 0.0401 and wR = 0.0984 for 3135 observed reflections (I> 2σ (I)). Single-crystal X-ray analysis revealed that the Co dimensional chain structure via phthalate bri-dging ligand. In the cobalt complex, a 3D network structure is formed by π-π stacking interaction of 1,10-phenanthroline as well as intermolecular hydrogen bonding interactions.