含农药配体的铜配合物的合成与介电性质(英文)

• 作 者: 钱坤 金杨波 李永绣
• 机 构: 南昌大学稀土与微纳功能材料研究中心,南昌大学稀土与微纳功能材料研究中心,南昌大学稀土与微纳功能材料研究中心 南昌330047,南昌330047,南昌330047
• 出 处: 无机化学学报
• 发表日期: 2006年09期
• 关键词: 铜配合物 晶体结构 介电性质 dielectric carboxylate fabrication carboxylic sharply coordinated

The hydrothermal treatment of 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol (CDTO) with Cu(OAc)2·4H2O in the presence of methanol as solvent offers a molecular coordination compound [Cu(CDTO)2(OAc)2] (1), whose dielectric physical properties has been investigated. Crystal data for 1: Triclinic, P1, a=0.859 06(10) nm, b=1.053 11(13) nm, c=1.202 96(14) nm. α=111.540(2)°, β=108.899(2)°, γ=196.249(3)°. V=0.925 09(19) nm3, Z=1, 3 579 unique data (θmax=25.99°), R=0.053 9 (2 888 [I≥2σ(I)] reflections), wR=0.154 1 (all data), ρmax=0.55 e·nm-3. CCDC: 605591.

The hydrothermal treatment of 1- (4-chlorophenoxy) -3,3-dimethyl-1- (1H-1,2,4- triazol- 1-yl) butan-2-ol (CDTO) with Cu (OAc) 2 · 4H2O in the presence of methanol as a solvent offers a molecular coordination compound [Cu (CDTO) 2 (OAc) 2] (1), whose dielectric physical properties have been investigated. Crystal data for 1: Triclinic, P1, a = 0.859 06 ( Α = 111.540 (2) °, β = 108.899 (2) °, γ = 196.249 (3) °. V = 0.925 09 (19) nm3, Z = 1, 3 579 unique data (θmax = 25.99 °), R = 0.053 9 (2 888 [I≥2σ (I)] reflections), wR = 0.154 1 e · nm-3. CCDC: 605591.