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可以生产宽范围的各种制药和农用化学品用单旋光异构体的手性催化技术将由 Johnson Matthey公司工业化。该催化剂为双金属铑基化合物内手性配位体配合在一起。将要工业化的催化剂是铑—铑化合物 ,其制备是将醋酸铑和氨基酸衍生物 (配位体 )在大约 1 30℃置于氯苯中混合而成。在
The chiral catalysis technology that can produce a wide range of single optical isomers for various pharmaceutical and agrochemicals will be industrialized by Johnson Matthey. The catalyst is a bimetallic rhodium-based compound within the chiral ligand coordination together. The catalyst to be industrialized is a rhodium-rhodium compound prepared by mixing rhodium acetate with an amino acid derivative (ligand) in chlorobenzene at about 130 ° C. in