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一些含有吗啉基的高聚物,作为含脂肪叔胺基的医用高分子材料而被瞩目。我们曾报道了N-(N′-次甲基吗啉)取代丙烯酰胺的合成,及其在过氧化二月桂酰引发下的聚合动力学。它的聚合规律和我们以往所报道的含脂肪叔胺基单体的聚合一样。本文合成了在同—分子中既含吗啉基,又含有羟基的丙烯酸脂,即甲基丙烯酸-2-羟基-3-吗啉基丙酯(HMPMA),研究了在过氧化二月桂酰(LPO)引发下的热聚合,以及在芳香酮作增感剂下的光聚合。关于HMPMA的合成,虽有所报道,但关于其表征,在过氧化
Some morpholine-containing polymers are attracting attention as medical polymer materials containing fatty tertiary amine groups. We have reported the synthesis of N- (N’-methinemorpholino) substituted acrylamide and its kinetics of polymerization under dilauroyl peroxide. Its polymerization rules are the same as those reported in our previous reports of fatty tertiary amine containing monomers. In this paper, an acrylic resin containing both morpholino and hydroxyl groups in the same molecule, ie, 2-hydroxy-3-morpholinylpropyl methacrylate (HMPMA), was synthesized. The effects of dilauroyl peroxide LPO), and photopolymerization of aromatic ketones as sensitizers. Although the synthesis of HMPMA has been reported, its characterization is based on peroxidation