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NR等【Synth Commun,2002,32:2307】 环氧化物和芳胺的乙腈溶液中加入三氯化铋,在氮气氛下宰温搅拌1.5h,柱色谱分离得反式D一胺基醇。13例收率94%,.-97%。 【陈越磊摘】S35-08碳环的氧化物铋(Ⅲ)离子催化选择性开环@陈越磊
NR et al [Synth Commun, 2002, 32: 2307] epoxide and arylamine in acetonitrile was added bismuth trichloride and stirred for 1.5 h at room temperature under a nitrogen atmosphere. The trans-D-amino alcohol was isolated by column chromatography. The yield of 13 cases was 94%, -97%. 【Chen Yuelei pick】 S35-08 Carbocyclic Bismuth (Ⅲ) Ion Selective Catalytic Ring Opening Chen Yue