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The two title complexes,[Cd{3,5-(NO2)2sal}(2,2′-bipy)]n 1 and [Mn{3,5-(NO2)2sal}(2,2′-bipy)]n 2 (3,5-(NO2)2sal=3,5-dinitrosalicylate,2,2′-bipy=2,2′-bipyridine),were synthesized by the hydrothermal reaction and structurally characterized. Complex 1 crystallizes in triclinic,space group P1,a=5.581(4),b=12.071(8),c=12.88(1),α=92.10(3),β=96.73(3),γ =102.02(2)°,C17H10N4O7Cd,Mr=494.69,V=841(1)3,Z=2,Dc=1.954 g/cm3,F(000)=488,μ =1.353 mm-1,R=0.0248 and wR=0.0761. Complex 2 crystallizes in monoclinic with space group P21/c,a=8.604(3),b=23.88(1),c=8.894(3),β=102.45(1)°,C17H10N4O7Mn,Mr=437.23,V= 1785(1) 3,Z=4,Dc=1.627 g/cm3,F(000)=884,μ=0.791 mm-1,R=0.0471 and wR=0.1250. Complex 1 possesses an infinite 1D polymeric chain structure consisting of the repeated basic four-membered ring units (Cd2O2) and eight-membered ring units (CdOCO)2. Compound 2 displays a linear 1D chain through Mn(Ⅱ) atoms and bridging carboxylate groups of 3,5-dinitrosalicylic acid ligands with the Mn…Mn separation of 4.472(2). The fluorescence properties and cyclic voltammetric behaviors of the complexes are also reported.
The two title complexes [Cd {3,5- (NO2) 2sal} (2,2’-bipy)] n1 and [Mn {3,5- (NO2) 2sal} n2 (3,5- (NO2) 2sal = 3,5-dinitrosalicylate, 2,2’-bipy = 2,2’-bipyridine) were synthesized by the hydrothermal reaction and structurally characterized. Complex 1 crystallizes in triclinic, space group P1 a = 5.581 b = 12.071 c = 12.88 1 a = 92.10 3 β = 96.73 3 γ = 102.02 2 ° C17H10N4O7Cd, Mr = 494.69, V = 841 (1) 3, Z = 2, Dc = 1.954 g / cm3, F (000) = 488, μ = 1.353 mm -1, R = 0.0248 and wR = 0.0761. Complex 2 crystallizes in monoclinic with space group P21 / c, a = 8.604 (3), b = 23.88 (1), c = 8.894 (3) , β = 102.45 (1) °, C17H10N4O7Mn, Mr = 437.23, V = 1785 3, Z = 4, Dc = 1.627 g / cm3, F (000) = 884, μ = 0.791 mm- 1, R = 0.0471 and wR = 0.1250. Complex 1 possesses an infinite 1D polymeric chain structure consisting of the repeated basic four -membered ring units (Cd2O2) and eight-membered ring units (CdOCO) 2. Compound 2 displays a linear 1D chain through Mn (II) atoms and bridging carboxylate groups of 3,5-dinitrosalicylic acid ligands with th e Mn ... Mn separation of 4.472 (2) . The fluorescence properties and cyclic voltammetric behaviors of the complexes are also reported.