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目的研究祖师麻的化学成分。方法采用硅胶柱色谱、Pre-TLC、Pre-HPLC等方法进行分离纯化,并通过理化常数和波谱数据分析进行结构鉴定。结果分离得到6个已知的木脂素类化合物,分别鉴定为(-)-松脂酚[(-)-pinoresinol,1]、(+)-丁香树脂酚[(+)-syringaresinol,2]、(+)-里立脂素B二甲醚[(+)-lirio-rosinol-B-dimethyl ether,3]、(+)-丁香树脂酚双葡萄糖苷[(+)-syringaresinol-di-O-β-D-glucoside,4]、罗汉松脂醇(matairesinol,5)、woonenosideⅪ(6)。结论化合物3、6为从瑞香属植物中首次分离得到,化合物4、5为从祖师麻中首次分离得到。
Objective To study the chemical composition of founder Shi Ma. Methods The compounds were separated and purified by silica gel column chromatography, Pre-TLC and Pre-HPLC. The structures were elucidated by physicochemical constants and spectral data analysis. Results Six known lignan compounds were isolated and identified as (-) - pinoresinol, 1], (+) - syringaresinol, (+) - liri-rosinol-B-dimethyl ether, 3], (+) - syringaresinol-bis-O- β-D-glucoside, 4], matairesinol (5), woonenoside XI (6). Conclusion Compounds 3 and 6 were isolated from the genus Daugther for the first time. Compounds 4 and 5 were isolated from the genus Symphylium for the first time.