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１９６５年，塞诺夫（Ｃ．Ｖ．Ｓｅｎｏｆｆ）和艾伦（Ａ．Ｄ．Ａｌｌｅｎ）第一次在水溶液中用肼和水合三氯化钉反应制得了过渡金属元素的双氮配合物即［ＲＵ（ＮＨ３）５Ｎ２］２＋。这一研究成果开辟了过渡金属配合物化学的新领域，在理论上对揭示生物固氮和氮、氢在常温常
In 1965, C.V.Senoff and A.D. Allen for the first time reacted with hydrazine trichloride hydrate in aqueous solution to prepare the dinitrogenated complex of transition metal elements [ RU (NH3) 5N2] 2+. This research has opened up a new field of transition metal complex chemistry, in theory to reveal biological nitrogen and nitrogen, hydrogen at room temperature often