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目的 研究新型卟啉四 (对 -癸酰氧基 )苯基卟啉锰配合物 [TDPPMn( ) Cl]的循环伏安性质 .方法 用元素分析、紫外可见光谱、红外光声光谱、摩尔电导和核磁共振氢谱等方法对配合物的结构进行了表征 ,用循环伏安法研究了[TDPPMn( ) Cl]在 DMSO溶液中的电化学性质 .结果 锰卟啉配合物中心离子由正三价还原为正二价的半波电位为 -0 .6 9V,卟啉环氧化还原的半波电位为 - 1.80 V,二步电极反应均可逆 .结论 新型卟啉四 (对 -癸酰氧基 )苯基卟啉锰配合物可作为一种理想的催化剂 .
Aim To study the cyclic voltammetry of a novel porphyrin tetrakis (p-decanoyloxy) phenyl porphyrin manganese complex [TDPPMn () Cl] .METHODS The cyclic voltammetry (CV) The structure of the complex was characterized by 1H-NMR and 1H-NMR spectra, and the electrochemical properties of [TDPPMn (Cl)] in DMSO solution were investigated by cyclic voltammetry.Results The central ion of the manganese porphyrin complex was reduced to The half-wave potential of positive divalent is -0.69V, the half-wave potential of epoxidation and reduction of porphyrin is -1.8 V, and the two-electrode reaction is reversible.Conclusion The novel porphyrin tetrakis (p-decanoyloxy) phenyl Porphyrin manganese complexes can be used as an ideal catalyst.