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金属卟啉在光合作用中起重要作用,合成其聚合物并作为光合作用模拟体系研究其能量转移和电子转移过程,已成为化学领域的重要研究课题之一.用于光合作用活性中心模拟体的金属卟啉聚合物种类很多,本文参考Little方法合成2种未见报道的苯环上分别带推电子和拉电子取代基和以柔韧碳氢链相连的中位双卟啉p-ZnTPP/p-H_2TMPP和p-ZnTPP/p-H_2TCPP(图1),探索了取
Metalloporphyrins play an important role in photosynthesis and the synthesis of their polymers and their energy transfer and electron transfer as a simulation system for photosynthesis have become one of the most important research topics in the field of chemistry. There are many kinds of metalloporphyrin polymers. In this paper, we report two little reported methods to synthesize p-ZnTPP / p-ZnTPP, which has been reported on the phenyl ring with electron donating and electron- H_2TMPP and p-ZnTPP / p-H_2TCPP (Figure 1) were explored