Synthesis and Crystal Structure of Zinc Complex [Zn(bipy)_3][Zn(SCN)_4]

• 出 处: 结构化学
• 发表日期: 2004年期
• 关键词: Zinc intriguing bonding interested stainless magnetism catalysis chemicals struc

The hydrothermal reaction of thiocyanate, 2,2?-bipyridine and ZnII in basified aqueous solutions gave rise to complex [Zn(bipy)3][Zn(SCN)4] 1 (C34H24N10S4Zn2) which was characterized by X-ray diffraction analysis. Crystal data for 1: monoclinic, space group P21/n, Mr= 831.61, Z = 4, a = 15.920(3), b = 13.5201(17), c = 17.362(3) ?, β = 99.467(9)o, V = 3686.1(10) ?3, Dc = 1.499 g/cm3, μ = 1.568 mm-1, F(000) = 1688, R = 0.0586 and wR = 0.1354 for 5604 observed reflections (I > 2σ(I)). The photoluminescence spectrum for the title compound has also been studied.

The hydrothermal reaction of thiocyanate, 2,2? -bipyridine and ZnII in basified aqueous solutions gave rise to complex [Zn (bipy) 3] [Zn (SCN) 4] 1 (C34H24N10S4Zn2) which was characterized by X-ray diffraction analysis. Crystal data for 1: monoclinic, space group P21 / n, Mr = 831.61, Z = 4, a = 15.920 (3), b = 13.5201 (17), c = 17.362 (3) , V = 3686.1 (10)? 3, Dc = 1.499 g / cm3, μ = 1.568 mm- 1, F (000) = 1688, R = 0.0586 and wR = 0.1354 for 5604 observed reflections (I> 2σ (I) The photoluminescence spectrum for the title compound has also been studied.