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利用原子转移自由基聚合技术合成了相对分子质量可控、相对分子质量分布较窄的丙烯酸叔丁酯与氟烷基（甲基）丙烯酸酯的嵌段共取物。进一步将嵌段共聚物的丙烯酸叔丁酯链段在酸性条件下水解，制备了水溶性含氟嵌段共聚物。借助核磁共振氢谱和红外光谱对嵌段共聚物进行了表征。
The block copolymer of t-butyl acrylate and fluoroalkyl (meth) acrylate with relatively controlled molecular weight and relatively narrow molecular weight distribution was synthesized by atom transfer radical polymerization. The tert-butyl acrylate segment of the block copolymer was further hydrolyzed under acidic conditions to prepare a water-soluble fluorine-containing block copolymer. The block copolymer was characterized by 1H - NMR and IR spectra.