【摘 要】
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Time-resolved IR absorption spectroscopy has been used to atudy the photochemistry of W(CO)_6 in cyclohexane, carbon tetrachloride, and the mixture of carbon t
【出 处】
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Chinese Chemical Letters
论文部分内容阅读
Time-resolved IR absorption spectroscopy has been used to atudy the photochemistry of W(CO)_6 in cyclohexane, carbon tetrachloride, and the mixture of carbon tetrachloride and cyelohexane. The reastion of photolytically generated W(CO)_5. C_6H_(12) with CCl_4 was investigated. An intermediate with a lifetime of about 0.5ms, presumably attributed as W(GO)_5.CCl_4, was first observed.
Time-resolved IR absorption spectroscopy has been used to investigate the photochemistry of W (CO) _6 in cyclohexane, carbon tetrachloride, and the mixture of carbon tetrachloride and cyelohexane. The reastion of photolytically generated W (CO) _5.C_6H_ (12) with CCl_4 was investigated. An intermediate with a lifetime of about 0.5ms, presumably attributed as W (GO) _5.CCl_4, was first observed.
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