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测定了八-4-(四氢糠氧基)双酞菁钕在亚相水面上的π-A曲线,在石英和高取向热解石墨(HOPG)基底上制备了它的LB膜,解释了八-4-(四氢糠氧基)双酞菁钕的UV-Vis谱带.并采用扫描隧道显微镜方法观察了LB膜的形貌,发现在HOPG上双酞菁钕分子是随机分布并有多聚体形成而在HOPG上修饰一层硬脂酸后可得到均匀有序单分散的双酞菁钕分布.所有结果表明大环分子垂直于基底排列
The π-A curve of octa-4- (tetrahydrofurfuryloxy) bisphthalocyanine neodymium on the subfacial water surface was determined. Its LB film was prepared on quartz and highly oriented pyrolytic graphite (HOPG) substrates, UV-Vis band of octa-4- (tetrahydrofurfuryloxy) bisphthalocyanine neodymium. The morphologies of LB films were observed by scanning tunneling microscopy. It was found that neodymium phthalocyanine molecules were randomly distributed on HOPG and formed multimers. After modification of HOPG with a layer of stearic acid, uniform and monodispersed Of the distribution of neodymium bisphthalocyanine. All the results show that the macrocyclic molecules are arranged perpendicular to the substrate