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合成了2个配位聚合物{[Cd(btaa)(phen)(CH3COO)].H2O}n(1)和{[Ag2(btaa)(4,4-bpy)2](NO3).2H2O}n(2)(Hbtaa=1H-苯并三氮唑-1-乙酸,phen=1,10-邻菲啰啉,4,4-bpy=4,4-联吡啶),采用单晶X-射线、红外光谱、元素分析和热重分析对配合物进行了表征。配合物1中的镉离子通过1H-苯并三氮唑-1-乙酸根桥连成一维螺旋链状结构。在配合物2中,银离子被4,4-联吡啶连接成一维链状结构,这些一维链通过1H-苯并三氮唑-1-乙酸根桥连以及Ag...Ag作用和π-π堆积连接成一维梯子状结构。此外,还研究了配合物1的荧光性质。
Two coordination polymers {[Cd (btaa) (phen) (CH3COO)]. H2O} n (1) and {[Ag2 (btaa) (4,4-bpy) 2] (NO3) (2) (Hbtaa = 1H-benzotriazole-1-acetic acid, phen = 1,10- phenanthroline, 4,4-bpy = , IR spectra, elemental analysis and thermogravimetric analysis. The cadmium ions in the complex 1 are bridged by 1H-benzotriazole-1-acetate into a one-dimensional helical chain structure. In complex 2, the silver ions are connected by 4, 4-bipyridines into one-dimensional chain structures, which are linked by 1 H-benzotriazole-1 -acetate bridge and Ag ... Ag and π -π stacking connected into a one-dimensional ladder-like structure. In addition, the fluorescence properties of complex 1 were also studied.