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电子自旋共振(ESR)实验间接表明,γ射线辐照能在室温下在BaF2微晶中产生Frenkel激子这样的元激发,此元激发受热在150℃以下消失。γ射线辐照使BaF2微晶中F-离子上的2P电子跃迁到外层轨道,并与2P轨道的空穴形成紧束缚的电子-空穴对——Frenkel激子。激子中的电子受热脱离F原子,这种晶格上的F0是ESR可探测的顺磁色心点缺陷——Vk心。受γ射线辐照的BaF2微晶中含有Frenkel激子,受热时Frenkel激子湮灭。Vk心增多的现象,表现为随温度增高Vk心的ESR信号增强的反常现象。
Electron spin resonance (ESR) experiments indirectly show that γ-ray irradiation can generate a meta-excitation of Frenkel exciton in BaF2 crystallites at room temperature, and the elemental heat disappears below 150 ° C. γ-ray irradiation causes the 2P electrons on the F- ions in the BaF2 crystallites to transition to the outer orbit and form tight tethered electron-hole pairs - Frenkel excitons with the holes in the 2P-orbitals. The electrons in the exciton are heated away from the F atom, and F0 on this lattice is the paramagnetic color point defect of the ESR detectable - the Vk heart. Frenkel excitons are contained in γ-ray-irradiated BaF2 crystallites and annihilated by Frenkel excitons when heated. Vk increased heart phenomenon, manifested as increased temperature Vk heart ESR signal enhancement anomaly.