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Ordered mesoporous copper incorporated Al2O3 (Cu/Al2O3) with high Cu dispersion were prepared by a facile solution combustion synthesis method using aluminum nitrate and copper nitrate as oxidants and urea as fuel.It is a facile and green route to synthesize catalysts for dimethyl ether directly from syngas.Cu/Al2O3 catalysts were characterized by XRD,N2 adsorption-desorption,SEM-EDS,and H2-TPR.The results indicate that the catalysts obtain an ordered mesoporous structure and copper is homogenously dispersed.The mesoporous Cu/Al203 catalysts were utilized as bifunctional catalysts in syngas to dimethyl ether reaction (STD).The copper content affects the catalytic performance in STD reaction.The CO conversion and DME selectivity of Cu/Al2O3 with 15％ copper molar ratio achieve 52.9％ and 66.1％,respectively.Moreover,the mesoporous Cu/Al2O3 catalysts show excellent stability in STD reaction.