,Synthesis and characterization of the B3-monomer and hyperbranched poly(aryl ether ketone)s

• 作 者: Mu Jianxin Zhang Chunling Wang Zou Chen Jie Jiang Zhenhua
• 机 构: College of Chemistry,Jilin University,Changchun 130012,China“,”College of Materials Science and Engi
• 出 处: 中国高等学校学术文摘·化学
• 发表日期: 2006年2期
• 关键词: B3 monomer hyperbranched poly(ether etherketone)s hydroxyl-terminated fluoro-ter

Hyperbranched poly(aryl ether ketone)s were prepared by polymerization of hydroquinone(A2)and 1,3,5-tris[4-(4-fluorobenzoyl)phenoxy]benzene (B3).The gelation of hyperbranched poly(aryl ether ketone)s was effectively avoided.Hydroxyl-terminated(HPAEK-OH)and fluoro-terminated (HPAEK-F) hyperbranched poly(aryl ether ketone)s were prepared by using different A2/B3 mass ratio.The structure of the B3 monomer was confirmed by MS,1H NMR/IR.The glass transition temperatures of the HPAEK-F and HPAEK-OH are 114℃ and 162℃ respectively.Thermal stability of HPAEK-F is higher than HPAEK-OH.