三(2-甲基-2-苯基丙基)锡羧酸酯的合成、结构表征和生物活性

• 作 者: 张树奎 陈学仁 李之春 谢庆兰 张招贵 邓锋杰
• 机 构: 南开大学元素有机化学国家重点实验室!天津,300071,南开大学元素有机化学国家重点实验室!天津,300071,南开大学元素有机化学国家重点实验室!天津,300071,南开大学元素有机化学国家重点实验
• 出 处: 高等学校化学学报
• 发表日期: 1999年11期
• 关键词: 苯丁锡 羧酸酯 结构表征 生物活性测定 杀螨活性

Fifteen tris(2 dimethyl 2 phenylpropyl)tin carboxylates were synthesized and characterized by IR and 1H NMR. The results showed that these compounds may be four coordinated and there are a linear relationship between Δν CO 2 and the Hammett constants ( σ) of the para substituents of the corresponding substituted benzoates. The bioasay tests show that neophyltin derivatives have a good acaricidal activity and may provide an acaricide for the better activity and economy.

Fifteen tris (2 dimethyl 2 phenylpropyl) tin carboxylates were synthesized and characterized by IR and 1H NMR. The results showed that these compounds may be four coordinated and there are a linear relationship between Δν CO2 and the Hammett constants (σ) of the para substituents of the corresponding substituted benzoates. The bioasay tests show that neophyltin derivatives have a good acaricidal activity and may provide an acaricide for the better activity and economy.