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We report here the first measurements of momentum profiles for the propane (C3H8)valence orbitals using high resolution (△E=0.9 eV FWHM, △p=0.1 a.u.) (e,2e) electron momentum spectrometer. The impact energy was 1200 eV with binding energy l206 to 1232 eV andsymmetric non-coplanar kinematics was employed. The inner-valence spectrum is in agreementwith published photoelectron data. Excited ionic states corresponding to many-body electron correlation processes were observed for propane above 25 eV. The expeyimental momentum profileswere compared with calculations obtained using Hartree-Fock method with the minimum basis setand a high-level basis set, and also using density functional theory (DFT) local density and nonlocal density methods with a high level basis set. The agreement between theory and experimentfor the shape of orbital electron momentum distributions is generally good.