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含多原子桥联异双核配合物的研究对阐明生物体中的电子转移过程以及金属酶活性中心的本质有重要意义,基于草酰胺根的有效成桥功能,Kahn使用N,N′-双(3-氨丙基)草酰胺合铜(Cu(oxpn))作为双齿单核断片合成了双铜配合物[Cu(oxpn)Cu(bpy)](ClO_4)_2,最近,在我们实验室也用此单核断片合成了端接phen、NO_2-phen的双铜配合物和端接不同配体
Studies with polyatomic bridging heterobinuclear complexes are important for elucidating the electron transfer process in organisms and the nature of metalloenzyme activity centers. Based on the effective bridging function of oxalate roots, Kahn used N, N’-bis Cu (oxpn) Cu (bpy)] (ClO_4) _2 was synthesized as a bidentate mononuclear fragment and recently in our laboratory With this mononuclear fragment, the bis-copper complexes terminated with phen and NO_2-phen were synthesized and terminated by different ligands