Rhodium catalyzed asymmetric Pauson-Khand reaction using SDP ligands

• 作 者: FAN Baomin LI Shen XIE Jianhua
• 机 构: StateKeyLaboratoryofAppliedOrganicChemistry
• 出 处: 中国科学：化学英文版
• 发表日期: 2006年1期
• 关键词: Pauson-Khand reaction ASYMMETRIC catalysis DIPHOSPHINE ligand rhodium. Pauson
• 基金项目: This work was supported by the National Natural Science Foundation of China (Grant Nos. 20132010 and 20272026), the Major State Basic Research Development Program (Grant No. G2000077506), the Ministry

The activity and enantiocontrol ability of the chiral catalysts prepared from spiro diphosphine ligands, SDP, and rhodium precursor were investigated in the asymmetric catalytic Pauson-Khand reaction. The results showed that SDP ligands were very effectiv