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室温下 ,通过双核配合物 [Cu(dppm) (NO3 ) ]2 (dppm =双二苯基膦甲烷 )与四苯基硼钠在甲醇和二氯甲烷混合溶剂中反应制备了三核铜 (Ⅰ )配合物 [Cu3 (dppm) 3 (NO3 ) (OH) ](NO3 ) ,经过红外光谱、热重分析、核磁和ES MS等现代分析手段表征了配合物的物理化学性质 ,并进一步研究了配合物在室温下的荧光光谱特征
Trinuclear copper (Ⅰ) was prepared by reaction of dinuclear complex [Cu (dppm) (NO3)] 2 (dppm = bisdiphenylphosphinemethane) and sodium tetraphenylborate in methanol and dichloromethane at room temperature ) Complexes (Cu3 (dppm) 3 (NO3) (OH)] (NO3) were synthesized and characterized by IR, TG, NMR and ES MS. The physicochemical properties of the complexes were characterized, Fluorescence Spectral Characteristics of Materials at Room Temperature