Synthesis, characterization and structure of Re_2(μ-L')(CO)_6-L (L-L=Ph_2P-CH_2-CH_2-PPh_2, L&#

• 作 者: 高忆慈
• 机 构: Department of Chemistry, Lanzhou University, Lanzhou 730000, China
• 出 处: Chinese Science Bulletin
• 发表日期: 1995年08期
• 关键词: carbonyl readily unsaturated CO Cl or OCH_3 Synthesis and ReL latter entering em

Recently the emphasis of our studies on O-atom transfer reaction involves a type ofreaction:O atom transfers from EO to a carbonyl carbon and forms CO_2, which is a good leavinggroup and departs from the carbonyl, and a coordinatively unsaturated active intermediate“LmM(CO)_(n-1)L”. The latter readily reacts with E or the entering ligand L

Recently the emphasis on our studies on O-atom transfer reaction involves a type of act: O atom transfers from EO to a carbonyl carbon and forms CO_2, which is a good leaving group and departs from the carbonyl, and a coordinatively unsaturated active intermediate “LmM (CO) _ (n-1) L ”. The latter readily reacts with E or the entering ligand L