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光学活性聚甲基丙烯酸三苯甲酯是单手螺旋链构象的聚合物,其链构象具有较高的热稳定性。这样一个手性螺旋链聚合物的热学行为是人们所关心的。本实验室合成了光学活性聚甲基丙烯酸三苯甲酯(PTrMA),聚甲基丙烯酸邻甲基苯基二苯甲酯(o-PDPTMA),聚甲基丙烯酸邻甲氧基苯基二苯甲酯(PMTrMA)和聚甲基丙烯酸对甲基苯基二苯甲酯(p-
Optically active triphenylmethyl polymethacrylate is a one-handed helical conformational polymer with a higher thermal stability of the chain conformation. The thermal behavior of such a chiral helical polymer is of concern. The lab synthesized optically active poly (triphenylmethyl) acrylate (PTrMA), poly (o-methylphenyl) phenylmethacrylate (o-PDPTMA), o-methoxyphenyldiphenylmethacrylate Methyl methacrylate (PMTrMA) and p-methylphenyldiphenylmethacrylate (p-