Kinetics of photoelectrocatalytic degradation of endocrine disrupting chemicals using sulfur-doped T

来源 :Journal of Harbin Institute of Technology | 被引量 : 0次 | 上传用户:qwm777
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In this study,sulfur-doped TiO2 /Ti photoelectrodes were prepared by anodization. The morphology, crystalline structure,composition of sulfur-doped TiO2 /Ti film and light absorption property were examined by SEM,XRD,XRF,XPS and UV/VIS respectively. Dimethyl phthalate( DMP) ,one kind of environmental disrupting chemicals( EDCs) ,was degraded by the optimized photoelectrodes. Power of xenon light,initial concentration of DMP,photoelectrocatalytic( PEC) area of photoelectrode and bias were investigated in the study on kinetics of PEC degradation of DMP. Hence,this study concluded that the optimum conditions were power of xenon light 150 W,initial concentration of DMP 1 mg/L,PEC area of sulfur-doped TiO2 /Ti photoelectrode 10 cm2,bias 1. 3 V in the PEC reaction system. The morphology, crystalline structure, composition of sulfur-doped TiO2 / Ti film and light absorption properties were examined by SEM, XRD, XRF, XPS and UV / VIS . Dimethyl phthalate (DMP), one kind of environmental disrupting chemicals (EDCs), was degraded by the optimized photoelectrodes. Power of xenon light, initial concentration of DMP, photoelectrocatalytic (PEC) area of ​​photoelectrode and bias were investigated in the study on kinetics of PEC degradation of DMP. This study was concluded that the optimum conditions were power of xenon light 150 W, initial concentration of DMP 1 mg / L, PEC area of ​​sulfur-doped TiO2 / Ti photoelectrode 10 cm2, bias 1. 3 V in the PEC reaction system.
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