A Novel Octahedral Hexasilver(I) Cluster: Ag_6[SSCN(n-C_4H_9)_2]_6

来源 :Chinese Journal of Chemistry | 被引量 : 0次 | 上传用户:jimislg
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The first crystal structural report of a AgDTC complex (DTC= dialkyldithiocarbamate, R= n butyl) presented in this paper shows that it is a hexanuclear species. The structural arrangement for the DDP (dialkyldithiophosphate) ligands is different from that of Cu 6(DDP) 6, but is the same as that of Ag 6 [SSP(O i Pr) 2] 6. The first crystal structural report of a AgDTC complex (DTC = dialkyldithiocarbamate, R = n butyl) presented in this paper shows that it is a hexanuclear species. The structural arrangement for the DDP (dialkyldithiophosphate) ligands is different from that of Cu 6 (DDP ) 6, but is the same as that of Ag 6 [SSP (O i Pr) 2] 6.
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