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无溶剂条件下烯丙基异构化的改进ThachLN等[SynCommun1993;23(10):1379]对黄樟素及乙基丁子香酚中烯烃异构化(RCH2-CH=CH2→RCH=CHCH3)条件进行了研究。其较佳反应条件是不加溶剂用KOH在催化量PTC存在下,...
Improvement of allylic isomerization under solvent-free conditions ThachLN et al [SynComm 1993; 23 (10): 1379] performed the isomerization (RCH2-CH = CH2 → RCH = CHCH3) of alkenes in safrole and ethyl eugenol Study. The better reaction conditions are without solvent KOH in the presence of a catalytic amount of PTC, ...