Effects of cobalt substitution on structure and microwave absorption properties of PrNi_5 alloy

来源 :Journal of Rare Earths | 被引量 : 0次 | 上传用户:limajubo
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The polycrystalline samples PrNi_(5-x)Co_x(x=0.0,0.1,0.2,0.3,0.4) were synthesized by arc smelting and high energy ball milling method.The phase structure,morphology,saturation magnetization and electromagnetic parameters of the alloy powders were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),vibrating sample magnetometry(VSM) and vector network analyzer(VNA),respectively.The results revealed that the lattice parameter a and c and unit-cell volume V increased with the increasing amount of Co substitution.The saturation magnetization increased as Co content increased.The minimum absorption peak frequency shifted towards lower frequency region with the increasing amount of Co substitution.And the minimum reflection loss of the PrNi_(5-x)Co_x powders increased first and then decreased with the increasing amount of Co substitution.The PrNi_(5-x)Co_x alloys possessed the excellent microwave absorbing properties.The minimum reflection loss of the PrNi_(4.9)Co_(0.1) alloy all could reach-20.0 dB with the coating thickness ranging from 1.8 to 3 mm.The minimum reflection loss of PrNi_(4.9)Co_(0.1) powders was-36.20 dB at 7.76 GHz,and the frequency bandwidth of R<-10 dB reached about 1.50 GHz with the best matching condition d=2.0 mm. The polycrystalline samples PrNi_ (5-x) Co_x (x = 0.0,0.1,0.2,0.3,0.4) were synthesized by arc smelting and high energy ball milling method.The phase structure, morphology, saturation magnetization and electromagnetic parameters of the alloy powders were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), vibrating sample magnetometry (VSM) and vector network analyzer (VNA), respectively. These results revealed that the lattice parameter a and c and unit-cell volume V increased with the increasing amount of Co substitution. The minimum absorption peak frequency shifted towards lower frequency region with the increasing amount of Co substitution. And the minimum reflection loss of of PrNi_ (5-x) Co_x The amount of increased increase of Co substitution.The PrNi_ (5-x) Co_x alloys possessed the excellent microwave absorbing properties.The minimum reflection loss of the PrNi_ (4.9) Co_ (0.1) ) all all reach -20.0 dB with the coating thickness ranging from 1.8 to 3 mm.The minimum reflection loss of PrNi_ (4.9) Co_ (0.1) powders was-36.20 dB at 7.76 GHz, and the frequency bandwidth of R <-10 dB reached about 1.50 GHz with the best matching condition d = 2.0 mm.
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