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通过控电流沉积制备出纳米晶镍钼合金沉积层，沉积层的ＸＲＤ、ＸＰＳ结果表明，纳米晶镍钼合金沉积层存在较大的晶格畸变，其微晶尺寸为１７ｎｍ，纳米合金各元素的结合能发生了不同程度的位移．在３０％的ＫＯＨ溶液中纳米晶镍钼合金电极对析氢反应表现出较高的电催化活性．电化学交流阻抗谱表明，析氢过程按ＶｏｌｍｅｒＨｅｙｒｏｖｓｋｙ机理进行．
XRD and XPS results show that there is a large lattice distortion in the deposited layer of nanocrystalline nickel-molybdenum alloy with a crystallite size of 1.7 nm and a nano-sized Alloying elements can occur with different degrees of displacement. In 30% KOH solution, the nanocrystalline Ni-Mo alloy electrode shows higher electrocatalytic activity for hydrogen evolution reaction. Electrochemical AC impedance spectroscopy showed that the hydrogen evolution process was carried out according to the Volmer-Heyrovsky mechanism.