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在聚乙烯醇缩丁醛(PVB)薄膜中添加LMG及有机卤代物(RX),研制成功PVG剂量计,并对其性能作了探讨[1]。结果表明,60Coγ射线辐照能引发体系中隐色的LMG氧化生成绿色的孔雀绿(MG+),生成数量与吸收剂量成正比。通过改变基体中LMG或RX的浓度,可以获得不同的线性剂量响应关系(即单位厚度的吸光度差△A/L,mm-1与剂量,kGy之间的关系),对合理控制PVG剂量膜的组成具有指导意义。此外,还初步探讨了该体系的辐射变色机理。
In the polyvinyl butyral (PVB) film added LMG and organic halogen (RX), developed a successful PVG dosimeter, and its properties were discussed [1]. The results show that 60Co γ-ray irradiation can induce the leuco-LMG oxidation in the system to generate green malachite green (MG +), and the generated amount is proportional to the absorbed dose. By varying the concentration of LMG or RX in the matrix, different linear dose-response relationships (ie, the difference in absorbance per unit thickness ΔA / L, the relationship between mm-1 and dose, kGy) can be obtained, Composition is instructive. In addition, the mechanism of radiation discoloration of the system is also discussed preliminarily.