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一、绪言有机电解氧化合成(即用电解氧化进行有机合成)是电解合成的重要部分。它的历史已经很久了。1830年律多斯道夫(Lüdersdorff)首先对醇在不同电极上进行氧化,并对所生成的各种产物进行了详细的研究。1834年法拉第(Faraday)用醋酸钠水溶液电解生成乙烷。此反应在此15年后的1849年由柯尔贝
I. INTRODUCTION Organic electrolytic oxidation synthesis (that is, organic synthesis with electrolytic oxidation) is an important part of electrolytic synthesis. It’s been a long time ago. In 1830 Lüdersdorff first oxidized alcohols on different electrodes and studied the various products produced. In 1834 Faraday was electrolyzed with aqueous sodium acetate to produce ethane. This reaction was followed 15 years later by Kirby in 1849