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惰性化学键的活化与重组是近几年来非常热门的研究领域,同时这个领域也非常富有挑战性.本文以麻生明教授为首席的国家重点基础研究发展项目(973项目)“惰性化学键的选择性激活、重组及其控制”为基础,阐述了惰性碳-杂原子键,碳-氢键,碳-碳键,二氧化碳和氧气小分子四个方面的活化和重组,介绍了一些催化合成的新方法.这些新方法在完成惰性化学键活化和重组的同时,也注重于降低污染,使用更温和的条件,提高了原子经济性,为可持续发展战略提供了强有力的技术支持.
Activation and reorganization of inert chemical bonds are very popular in recent years, and the field is also very challenging. In this paper, the State Key Basic Research Development Project (973 Project) headed by Professor Aim Shengming is the key to the selectivity of inert chemical bonds Activation, Reorganization and Control ", the activation and recombination in four aspects of inert carbon - heteroatom, carbon - hydrogen bonding, carbon - carbon bond, carbon dioxide and oxygen are described. Method.These new methods, while completing the inert chemical bonding activation and recombination, also focus on reducing pollution, using milder conditions, improving atom economy and providing strong technical support for the sustainable development strategy.