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A Cu(Ⅱ) complex Cu(L)1.5(OSO3)·3H2O (1) L=1,4-bis(imidazol-1-yl)benzene was synthesized by reaction of ligand L with CuSO4·5H2O using solvothermal method and its structure was determined by X-ray crystal structure analysis. The structure indicates that the complex crystallizes in triclinic, space group P1 with a=0.948 8(2), b=1.078 5(2), c=1.108 4(2) nm, α=74.820(2), β=81.331(2), γ=72.638(2)°, V=1.041 5(3) nm3, Z=2, Dcalc=1.687 g·cm-3, F(000)=544, μ=1.205 cm-1, the final R=0.062 3 and wR=0.132 8. The Cu(Ⅱ) atom has distorted square-pyramidal environment with a N3O2 donor set. Each L ligand links two Cu(Ⅱ) atoms using its imidazole groups to form an infinite one-dimensional (1D) ladder-like chain, which further linked by SO42-to form a two-dimensional (2D) network structure. The 2D sheets are further connected by C-H…O hydrogen bonds to give a three-dimensional (3D) structure. CCDC: 650388.
A Cu (II) complex Cu (L) 1.5 (OSO3) · 3H2O (1) L = 1,4-bis The structure indicates that the complex crystallizes in triclinic space group P1 with a = 0.948 8 (2), b = 1.078 5 (2), c = 1.108 4 (2) nm, α = 74.820 (2) β = 81.331 (2) γ = 72.638 (2) ° V = 1.041 5 (3) nm3 Z = 2 Dcalc = 1.687 g · cm -3 F (000) = 544 , μ = 1.205 cm -1, the final R = 0.062 3 and wR = 0.132 8. The Cu (Ⅱ) atom has distorted square-pyramidal environment with a N 3 O 2 donor set. Each L ligand links two Cu imidazole groups to form an infinite one-dimensional (1D) ladder-like chain, which further linked by SO42-to form a two-dimensional (2D) network structure. three-dimensional (3D) structure. CCDC: 650388.