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研究了二个新的全氟烷基乙烯基醚7,7-二氯-3-氧杂全氟庚烯-1(M_0)和10,10-二氯-3,6-二氧杂全氟5-甲基癸烯-1(M_1)-与四氟乙烯(TFE)的共聚反应,聚合物的性质,并测定了TFE-M_0竞聚率。竞聚率的测定证明M_0较其它已报道的全氟烷基乙烯基醚的聚合活性都大。TFE-M_0共聚物通过化学反应可转化成相应的全氟羧酸甲酯树脂。
Two new perfluoroalkyl vinyl ethers 7,7-dichloro-3-oxa-perfluoroheptene-1 (M_0) and 10,10-dichloro-3,6-dioxa-perfluoro Copolymerization of 5-methyldecene-1 (M_1) - with tetrafluoroethylene (TFE), the properties of the polymer, and the reactivity ratio of TFE-M_0 were measured. The reactivity ratio of M_0 was higher than that of other reported perfluoroalkyl vinyl ethers. The TFE-M_0 copolymer can be converted to the corresponding perfluorocarboxylic acid methyl ester resin by chemical reaction.