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An electrochemical sensor for simultaneous detection of acetaminophen(APAP)and ascorbic acid(AA)is frstly developed by using the self-assembled flm of a novel dimeric bis(phthalocyaninato)europium complex,[{Pc(SC2H5)8}Eu{BiPc(SC2H5)12}Eu{Pc(SC2H5)8}](1)coated onto ITO(fm-1/ITO)fabricated through a solution-processing quasi-LangmuirSh(a)fer(QLS)protocol.