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This article mainly aims at the comparison of the Magnesia alumina spinel(MgAl2O4) phase synthesized by microwave sintering and conventional sintering respectively.Experiments were to measure and mix MgO powder and Al2O3 powder with mole ratio 1∶1, then to sinter the mixture powder by microwave sintering and conventional sintering respectively, and MgAl2O4 phase was got.