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Three dimensional highly hierarchical flower-like Bi2WO6 microspheres self aggregated by nanoplates have been fabricated in a green hydrothermal way at low temperature,without using any template or setting a certain pH value in solution.The formation mechanism as obtained flower-like Bi2WO6 microspheres were explored and their visible-light-driven photocatalytic performance were investigated,which indicated their high activity on degradation of organic dye under visible light irradiation.This cost effective way introduced to get well-organized flower-like Bi2WO6 microspheres shows potential application on water treatment field by full use of solar light.