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With Na2O-CaO-SiO2 glass as a matrix,we prepared light-conversion glass through high-temperature fusion technical.The glass we prepared doped Ce3+/Tm3+/Sm3+asactivation.We found that the strongest two emission peaks of Ce3+ are around 389nm and 415nm and both of them are broadband emission;Tm3+has two emission peaks which are around 450nm and 457nm;the emission peaks of Sm3+are around 562nm,599nm and 646nm.